Preparation and Photocatalytic Activity of Fe3+ - doped TiO2 Modified

Abstract

Photocatalytic materials of TiO2 / coarse silica gel microspheres were prepared by sol-gel impregnation method and doped with transition metal ions Fe3+ to form Fe3+ modified TiO2 / coarse silica gel microspheres. The surface of the Fe modified photocatalytic materials were analyzed by XRD and surface scanning. Degradation of reactive dyes using X-3B dye wastewater water samples for validation tests. The results show that the photocatalytic activity of the photocatalytic material reaches the best when the Fe doping amount is 0.5%, and the most photocatalyst amount is 10g / L. The degradation rate of COD under this dosage was 72.32%. At the same time, according to the characterization analysis, it was found that Fe did not react with the photocatalytic material of TiO2 / coarse silica microspheres in the reaction, Fe increased the defect structure of TiO2 surface and promoted the formation of anatase, A red shift occurred and the corresponding range of the spectrum expanded toward the visible region. The results show that the doping of Fe affects the formation of TiO2 crystals, but increases the photocatalytic efficiency of TiO2.